ESTIMATION OF THE TIME OF REACHING FIRE AND EXPLOSIVE CONCENTRATIONS IN THE ROOM WHEN A PROPANE-BUTANE CYLINDER IS DEPRESSURIZED
DOI:
https://doi.org/10.33042/2522-1809-2025-3-191-509-515Keywords:
propane-butane, fire and explosive concentration, time, gas leakageAbstract
The study was conducted in the context of military aggression, where the use of propane-butane by the population of Ukraine for cooking and heating has become particularly relevant due to periodic power outages. This situation creates additional threats, as the fire and explosion hazard of gas cylinders, particularly their depressurization due to critical pressure and temperature increases, is determined by several key factors. Incidents related to gas explosions regularly occur worldwide, causing significant material damage, infrastructure destruction, and, most importantly, human casualties.
The authors conducted a detailed analysis of the influence of the adiabatic coefficient and system pressure on the nature of gas leakage from the cylinder. The range of parameters under which the leakage is supercritical was determined. The use of the dependence for supercritical gas leakage from a gas cylinder is justified , as it is the most appropriate for calculating leakage parameters within the operating range of propane-butane cylinders (pressure
above 0.174 MPa). The analysis showed that when the coefficient changes from 1,13 to 1,15, the change in
( 0,5) Q/ S is no more than 1% , which allows the use of an averaged coefficient value without significant errors.
A key result of the study is the establishment of the dependence of the mass flow rate of gas from the cylinder
on the hole area and pressure in the event of possible depressurization. It was found that with a hole area of 1 mm2,
the gas flow rate ranges from 0,0012 to 0,0028 kg/s. This indicates that with small hole areas, gas leakage will be
insignificant, and the user may not notice it due to low flow rates. At the same time, the time to reach a fire and
explosive concentration critically depends on the hole area and can range from 20 seconds to 10000 seconds. For a
hole area of 1 mm2, the time to reach an explosive concentration is between 10 and 20 minutes. Gas ignition
(explosion) in a room is possible if the gas concentration in the room is within the range between the Lower
Flammability Limit (LFL) and Upper Flammability Limit (UFL). The obtained results are important for developing
effective preventive measures and monitoring systems aimed at preventing gas explosions and minimizing their
consequences.
References
Аналітична довідка про пожежі та їх наслідки в Україні за 12 місяців 2024 року. Київ, 2025. С. 39. Url: https://dsns.gov.ua/upload/2/3/0/1/6/1/2/analiticna-dovidkapro-pozezi-za-12-misiaciv-2024-na-sait.pdf
Аналітична довідка про пожежі та їх наслідки в Україні за 12 місяців 2023 року. Url: https://dsns.gov.ua/upload/2/0/2/2/3/2/1/2023-rik.pdf
ДСТУ IEC/ISO 31010:2013 Керування ризиком. Методи загального оцінювання ризику (IEC/ISO
:2009, IDT). Url: https://khoda.gov.ua/image/catalog/files/dstu%2031010.pdf
Turgut P., Gurel M., Pekgokgoz R. LPG explosion damage of a reinforced concrete building: A casestudy in Sanliurfa, Turkey. Engineering Failure Analysis. 2013. Vol. 32. P. 220-235. doi: 10.1016/j.engfailanal.2013.04.004
Krzysiak Z., Samociuk W., Bartnik G., Plizga K., Dziki D., Kaliniewicz Z., Nieoczym A., Wyciszkiewicz A., Otto T. Analysis of tank safety with propane-butane on LPG distribution station. Pol. J. Chem. Technol. 2017. Vol. 19. P. 99–102. doi: 10.1515/pjct-2017-0074
Baobin G., Wenjie Z., Chuangnan R., Shaopeng S., Chenhui G. Study of the effect of gas baffles on the prevention
and control of gas leakage and explosion hazards in autility tunnel. Applied Sciences. 2023. Vol.13. Iss. 7. P. 1-19. doi.org/10.3390/app13074264
Ismail M., Sharif K., Udin Z., Hassan M., Nawi M., Hamid Z., Ibrahim J., Othman A. A risk assessment in natural
gas supply. International Journal of Supply Chain Management. 2018. Vol.7. №4. P. 180-184. doi.org/10.59160/ijscm.v7i4.2371
Tindal J. Forensic engineering analysis of an explosion allegedly caused by an overfilled propane cylinder. Journal of the NAFE. 2018. Vol.35. № 2. P. 81-99. doi:10.51501/jotnafe.v35i2.62
Chmielewski R., Bąk A. Analysis of the safety of residential buildings under gas explosion loads. Journal of
Building Engineering. 2021. Vol.43. doi:10.1016/j.jobe.2021.102815
Tomlin G. Gas explosions in dwellings, the effects of interconnected rooms and obstacles, and the interpretation of thermal damage. 2015. P. 1-480. Url: https://etheses.whiterose.ac.uk/id/eprint/10599/
Ключка Ю.П. Визначення характеристик витікання газоподібного водню з балона / Ю.П. Ключка, В.І. Кривцова, В.Г. Борисенко // Проблеми пожежної безпеки. – Харків: НУЦЗУ, 2011. – № 29. – С. 84–91.
ДСТУ 4047-2001. Гази вуглеводневі скраплені паливні для комунального-побутового споживання. Технічні умови. Чинний від 01 січня 2002 р. Київ, 2001. 12 с. URL: https://online.budstandart.com/ua/catalog/docpage.html?id_doc=62241
ДСТУ EN ISO 8973:2013. Гази нафтові скраплені. Розрахунковий метод визначення густини і тиску пари (EN ISO 8973:1999, IDT). Чинний від 01 липня 2014 р. Київ, 2014. URL: https://online.budstandart.com/ua/catalog/docpage?id_doc=59285
Gas Encyclopedia. Air Liquide. URL: https://encyclopedia.airliquide.com/propane
Теорія розвитку й припинення горіння. Практикум. Частина IІ: / О.В. Тарахно, Д.Г. Трегубов, К.В. Жернокльов, А.І. Шепелева, В.В. Коврегін ─ Х.: НУЦЗУ, 2010. - 314 с.
Downloads
Published
Issue
Section
License
The authors who publish in this collection agree with the following terms:
• The authors reserve the right to authorship of their work and give the magazine the right to first publish this work under the terms of license CC BY-NC-ND 4.0 (with the Designation of Authorship - Non-Commercial - Without Derivatives 4.0 International), which allows others to freely distribute the published work with a mandatory reference to the authors of the original work and the first publication of the work in this magazine.
• Authors have the right to make independent extra-exclusive work agreements in the form in which they were published by this magazine (for example, posting work in an electronic repository of an institution or publishing as part of a monograph), provided that the link to the first publication of the work in this journal is maintained. .
• Journal policy allows and encourages the publication of manuscripts on the Internet (for example, in institutions' repositories or on personal websites), both before the publication of this manuscript and during its editorial work, as it contributes to the emergence of productive scientific discussion and positively affects the efficiency and dynamics of the citation of the published work (see The Effect of Open Access).