REPRODUCTION OF WASTE WATER CONTAMINATED BY IONS OF HEAVY METALS
Abstract
The article is devoted to the problem of wastewater treatment from ions of heavy metals. A brief review of methods of wastewater treatment from ions of heavy metals, their advantages and disadvantages is given. We investigated the possibility of extraction from wastewater of heavy metal ions by ultrafiltration-complexation in ultrafiltration mebrane. It is shown that in ultrafiltration the size of hydrated ions of all metals is much less than the diameter of the pore of the used membrane which makes it impossible to extract them from aqueous solutions.
However, if a high molecular weight component that forms a strong complex compound is introduced into the solution, the resulting polymer complex will be much larger than the diameter of membrane pore, which allows for separation on more large-pore and high-performance ultrafiltration membranes.
Instead of expensive synthetic polymers used environmentally friendly complexing agents derived from cheap natural raw materials (peat, brown coal) and having a high selective properties with respect to heavy metal ions. The results of the study are presented. It is concluded that the use of a method of treatment combining ultrafiltration with complexing using cheap chelating agents of natural origin, allows to increase the degree of purification of wastewater from heavy metal ions. To achieve the best results of water purification, this technology must be combined with other physicochemical and biological methods of water purification. These studies are relevant and bring novelty in the process of wastewater treatment.
Keywords: ions of heavy metals, cleaning of effluents, reactive, ion exchange, electrochemical, membrane methods, method of ultrafiltration, complexation.
References
Література
Тяжелые металлы [Электронный ресурс]. – Режим доступа: www. t-water.ru/index.php/ochistka-stochnykh-vod/91-tyazhelye-metally
Кашкина, Т.А. Влияние тяжелых металлов на биохимические процессы в организме [Текст] / Т.А. Кашкина // Научные достижения биологии, химии, физики: сб. ст. по матер. XII междунар. науч.-практ. конф. – Новосибирск: СибАК, 2012.
Лозановская, И. Н. Экология и охрана биосферы при химическом загрязнении [Текст]: учеб. пособие / И.Н. Лозановская, Д.С. Орлов, Л.К. Садовникова - М.: Высш. шк. – 1998. - 287 с.
Костюк, В.И. Очистка сточных вод машиностроительных предприятий [Текст] / В.И. Костюк, Г.С. Карнаух - К.: Тэхника, 1990.-120 с.
Штриплинг, Л.О. Основы очистки сточных вод и переработки твердых отходов [Текст]: учебное пособие / Л.О. Штриплинг, Ф.П. Туренко – Омск: Изд-во ОмГТУ, 2005. – 192 с.
Долина, Л.Ф. Проектирование и расчет сооружений и установок для физико-химической очистки производственных сточных вод [Текст]: учебное пособие / Л.Ф. Долина – Д.: Континент,2004. - 227с.
Долина, Л.Ф. Современная техника и технологии для очистки сточных вод от солей тяжелых металлов [Текст]: Монография / Л.Ф. Долина – Дн-вск.: Континент, 2008. - 254 с.
Пимнева, Л.А. Очистка сточных вод от токсичных тяжелых металлов [Электронный ресурс] / Л.А. Пимнева // Современные наукоемкие технологии. – 2013. – № 2. – С. 99-101. Режим доступа:
http://www.top-technologies.ru/ru/article/view?id=31338 (дата обращения: 10.03.2018).
Радовенчик, В.М. Малоотходная ионообменная технология очистки гальваностоков от ионов цинка [Текст] / В.М. Радовенчик, Я.В. Радовенчик // Эко- технологии и ресурсосбережение. – 2006. – № 5. – С. 60–63.
Варламова, С.И. Экологическая безопасность предприятий машиностроения (Обзор современного состояния проблемы) [Текст] / С.И. Варламова, Е.С. Климов // Изв. вузов. Северо-Кавказский регион. Технические науки. – 2005. – Приложение № 2. – С. 163–168.
Гребенюк, В. Д. Электрохимическая очистка воды [Текст] / В.Д. Гребенюк, Л.Х. Жигинас // ХиТВ. – 1998. – Т. 20, – № 2. - С. 152-164
Клименко, Т.В. Очистка сточных вод от ионов тяжелых металлов [Электронный ресурс] / Т.В. Клименко // Современные научные исследования и инновации. - 2013. - № 11. Режим доступа:
http://web.snauka.ru/issues/2013/11/28484 (дата обращения: 11.01.2018).
Ультрафильтрация. [Текст] / М.Т. Брык, В.А. Цапюк; Отв. ред. Пилипенко А.Т.; АН УССР. Ин-т коллоид. химии воды им. А.В. Думанского.- Киев: Наук. думка, 1989.-288 с.
References
Heavy metals. (n.d.) Retrieved from www. t-water.ru/index.php/ochistka-stochnykh-vod/91-tyazhelye-metally
Kashkina, TA (2012). Influence of heavy metals on biochemical processes in an organism: the collapsible article on materials of XII of international research and practice conference. Novosibirsk: SinAk.
Lozanovskaya, IN, Orlov, DS, Sadovnikova, LK.( 1998) Ecology and guard of biosphere at chemical contamination: train aid.: Higher school, 287.
Kostiuk, V.I, Karnauh, GS. (1990) Cleaning of effluents of machine-building enterprises. К.: Technique, 120.
Shtripling, LO, Turenko, FP (2005) Bases of cleaning of effluents and processing of hard wastes. Train aid. Omsk: publishing House Omsk State technical university, 192.
Dolyna, LF (2004). Planning and calculation of building and options for the physical and chemical cleaning of productive effluents : train aid. Continent, 227.
Dolyna, LF (2008). Modern technique and technologies for cleaning of effluents from salts of heavy metals: Monograph. Continent, 254.
Pimneva, L.A. (2013) Wastewater treatment from toxic heavy metals. Modern high technology, 2, 99-101. Retrieved from www.top-technologies.ru/en/article/view?id=31338 (reference date: 03/10/2018).
Radovenchik, VM, Radovenchik, Ya.V. (2006) Low-waste ion-exchange technology for cleaning galvanic rocks from zinc ions. Eco-technologies and resource-saving, 60-63.
Varlamova, SI, Klimov, E.S. (2005) Environmental safety of machine building enterprises (Review of the current state of the problem). North-Caucasian region. Technical science, 2,163-168.
Grebenyuk, VD, Zhiginas, L. Kh. (1998) Electrochemical purification of water. KhTVV, 20(2), 152-164
Klimenko, TV. (2013) Wastewater treatment from heavy metal ions. Modern scientific research and innovation. Retrieved from web.snauka.ru/issues/2013/11/28484 (date of circulation: 11/01/2018).
Bryk, MT, Tsapyuk, VA; Otv. Ed. Pilipenko, AT (1989) Ultrafiltration. Academy of Sciences of Ukraine. Institute of Colloid. chemistry of water. A.V. - Kiev: Naukova Dumka, 288.
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